Management and diagnostic of productive efficiency in a biorefinery of oils obtained by supercritical fluid extraction from grape and lucuma seeds

Authors

DOI:

https://doi.org/10.17268/agroind.sci.2026.02.03

Keywords:

Supercritical extraction, process simulation, Life Cycle (LCI), process sustainability, circular economy

Abstract

This This paper presents a comprehensive diagnosis of an industrial biorefinery dedicated to obtaining oils from grape and lucuma seeds, using supercritical carbon dioxide (SCD) as a green solvent. The analysis was carried out using a simulation model in SuperPro Designer, which allowed three essential aspects to be examined: operational performance, mass efficiency, and the environmental impact of the process. The results showed an overall efficiency of 1.73%, affected by limitations in the drying (TDR-102) and shelling (SR-101) stages, which reduce production capacity to 12.7% of the theoretical potential. The water footprint was 103 kg of water per kilogram of oil, and the waste index reached 0.03 kg/kg of raw material, indicating the need to improve resource management. The model allowed for the proposal of optimization measures focused on process intensification, raw material standardization, and dynamic control with artificial intelligence support. Overall, the results show that process simulation combined with sustainability indicators can guide the development of biorefineries under a circular economy approach.    

References

Aizpurua‐Olaizola, O., Ormazabal, M., Vallejo, A., Olivares, M., Navarro, P., Etxebarria, N., & Usobiaga, A. (2015). Optimization of Supercritical Fluid Consecutive Extractions of Fatty Acids and Polyphenols from Vitis Vinifera Grape Wastes. Journal of Food Science, 80(1). https://doi.org/10.1111/1750-3841.12715

Akterian, S., Fikiin, K., Georgiev, G., & Terziev, A. (2025). Pre-Treatment Equipment for Processing Grape Marc into Valorised By-Products: A Review. Sustainability, 17(13), 6188. https://doi.org/10.3390/su17136188

Aranda-Barradas, J. S., Guerrero-Barajas, C., & Ordaz, A. (2025). Addressing Challenges in Large-Scale Bioprocess Simulations: A Circular Economy Approach Using SuperPro Designer. Processes, 13(7), 2259. https://doi.org/10.3390/pr13072259

Brunner, G. (2005). Supercritical fluids: Technology and application to food processing. Journal of Food Engineering, 67(1), 21-33. https://doi.org/10.1016/j.jfoodeng.2004.05.060

Cari, M. (2018). Extracción y caracterización de almidón de las semillas de lúcuma (Pouteria lúcuma). Tesis de Licenciatura. Universidad Peruana Unión.

Chauca-Cerrutti, A., Inga, M., Pasquel-Reátegui, J. L., Betalleluz-Pallardel, I., & Puma-Isuiza, G. (2024). Optimization of extraction in supercritical fluids in obtaining Pouteria lucuma seed oil by response surface methodology and artificial neuronal network coupled with a genetic algorithm. Frontiers in Chemistry, 12, 1491479. https://doi.org/10.3389/fchem.2024.1491479

Chemat, F., Abert Vian, M., Fabiano-Tixier, A.-S., Nutrizio, M., Režek Jambrak, A., Munekata, P. E. S., Lorenzo, J. M., Barba, F. J., Binello, A., & Cravotto, G. (2020). A review of sustainable and intensified techniques for extraction of food and natural products. Green Chemistry, 22(8), 2325-2353. https://doi.org/10.1039/C9GC03878G

Chojnacka, K. (2023). Valorization of biorefinery residues for sustainable fertilizer production: A comprehensive review. Biomass Conversion and Biorefinery, 13(16), 14359-14388. https://doi.org/10.1007/s13399-023-04639-2

Duba, K., & Fiori, L. (2019). Supercritical CO2 extraction of grape seeds oil: Scale-up and economic analysis. International Journal of Food Science and Technology, 54(4), 1306-1312. https://doi.org/10.1111/ijfs.14104

FAO. (2023). The State of Food and Agriculture 2023. FAO; https://openknowledge.fao.org/handle/20.500.14283/cc7724en

Gaalich, I., Lee, D., Aymonier, C., Sonnemann, G., Olchowka, J., Philippot, G., & Loubet, P. (2026). Environmental impacts of supercritical fluids processes: A critical review of life cycle assessment studies. Environmental Impact Assessment Review, 116, 108106. https://doi.org/10.1016/j.eiar.2025.108106

Gojiya, D., & Gohil, V. (2022). Design and development of low cost sesame dehuller and its process standardization. Journal of Food Science and Technology, 59(11), 4446-4456. https://doi.org/10.1007/s13197-022-05524-y

Gombau, J., Pons‐Mercadé, P., Conde, M., Asbiro, L., Pascual, O., Gómez‐Alonso, S., García‐Romero, E., Miquel Canals, J., Hermosín‐Gutiérrez, I., & Zamora, F. (2020). Influence of grape seeds on wine composition and astringency of Tempranillo, Garnacha, Merlot and Cabernet Sauvignon wines. Food Science & Nutrition, 8(7), 3442-3455. https://doi.org/10.1002/fsn3.1627

Guerrero-Castillo, P., Reyes, S., Robles, J., Simirgiotis, M. J., Sepulveda, B., Fernandez-Burgos, R., & Areche, C. (2019). Biological activity and chemical characterization of Pouteria lucuma seeds: A possible use of an agricultural waste. Waste Management, 88, 319-327. https://doi.org/10.1016/j.wasman.2019.03.055

Häussling Löwgren, B., Hoffmann, C., Vijver, M. G., Steubing, B., & Cardellini, G. (2025). Towards sustainable chemical process design: Revisiting the integration of life cycle assessment. Journal of Cleaner Production, 491, 144831. https://doi.org/10.1016/j.jclepro.2025.144831

Ibrahim, S. N., Asnawi, A. L., Malik, N. A., Mohd Azmin, N. F., Jusoh, A. Z., & Mohd Isa, F. N. (2018). Web based Water Turbidity Monitoring and Automated Filtration System: IoT Application in Water Management. International Journal of Electrical and Computer Engineering (IJECE), 8(4), 2503. https://doi.org/10.11591/ijece.v8i4.pp2503-2511

Jokić, S., Bijuk, M., Aladić, K., Bilić, M., & Molnar, M. (2016). Optimisation of supercritical CO2 extraction of grape seed oil using response surface methodology. International Journal of Food Science & Technology, 51(2), 403-410. https://doi.org/10.1111/ijfs.12986

Laqui-Estaña, J., Obreque-Slier, E., García-Nauto, N., & Saldaña, E. (2024). Advances in Grape Seed Oil Extraction Techniques and Their Applications in Food Products: A Comprehensive Review and Bibliometric Analysis. Foods, 13(22), 3561. https://doi.org/10.3390/foods13223561

Lavenburg, V. M., Rosentrater, K. A., & Jung, S. (2021). Extraction Methods of Oils and Phytochemicals from Seeds and Their Environmental and Economic Impacts. Processes, 9(10), 1839. https://doi.org/10.3390/pr9101839

Luo, Q., Huang, X., Wu, J., Mou, X., Xu, Y., Li, S., Ma, G., Wan, F., & Peng, L. (2024). Simulation analysis and parameter optimi-zation of seed–flesh separation process of seed melon crushing and seed extraction separator based on DEM. Agriculture, 14(7), 1008. https://doi.org/10.3390/agriculture14071008

MIDAGRI. (2024). Perfil Productivo Regional [Visualización interactiva]. SIEA - Sistema Integrado de Estadística Agraria.

Ng, H. S., Kee, P. E., Yim, H. S., Chen, P.-T., Wei, Y.-H., & Chi-Wei Lan, J. (2020). Recent advances on the sustainable approaches for conversion and reutilization of food wastes to valuable bioproducts. Bioresource Technology, 302, 122889. https://doi.org/10.1016/j.biortech.2020.122889

Petrides, D., Sapidou, E., & Calandranis, J. (1995). Computer‐aided process analysis and economic evaluation for biosynthetic human insulin production—A case study. Biotechnology and Bioengineering, 48(5), 529-541. https://doi.org/10.1002/bit.260480516

Prado-Acebo, I., Cubero-Cardoso, J., Lu-Chau, T. A., & Eibes, G. (2024). Integral multi-valorization of agro-industrial wastes: A review. Waste Management, 183, 42-52. https://doi.org/10.1016/j.wasman.2024.05.001

Sheldon, R. A. (2007). The E Factor: Fifteen years on. Green Chemistry, 9(12), 1273-1283. https://doi.org/10.1039/B713736M

Subramaniyan, M., Skoogh, A., Bokrantz, J., Sheikh, M. A., Thürer, M., & Chang, Q. (2021). Artificial intelligence for throughput bottleneck analysis – State-of-the-art and future directions. Journal of Manufacturing Systems, 60, 734-751. https://doi.org/10.1016/j.jmsy.2021.07.021

Trost, B. M. (1995). Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way. Angewandte Chemie International Edition in English, 34(3), 259-281. https://doi.org/10.1002/anie.199502591

Vignesh., K., R., A., Rao G., P. K., Balan, S., B.M., J. A., Sales, E. A., R., A. P., & Aranda, D. A. G. (2023). A cascaded biorefinery for the sustainable valorization of Arthrospira maxima biomass: A circular bioeconomy approach. Bioresource Technology Reports, 23, 101510. https://doi.org/10.1016/j.biteb.2023.101510

Yıldırım, M., Erşatır, M., Poyraz, S., Amangeldinova, M., Kudrina, N. O., & Terletskaya, N. V. (2024). Green Extraction of Plant Materials Using Supercritical CO2: Insights into Methods, Analysis, and Bioactivity. Plants, 13(16), 2295. https://doi.org/10.3390/plants13162295

Zhang, L., Zhang, A., Zhou, S., Wang, Q., Wang, W., Ma, H., & Zhou, C. (2023). Real-time online monitoring technology for sweeping frequency ultrasound (SFU) assisted extraction of amur grape (Vitis amurensis) seed oil. Ultrasonics Sonochemistry, 100, 106621. https://doi.org/10.1016/j.ultsonch.2023.106621

Published

2026-04-08

How to Cite

Huayta Socantaype, F. V., & Napan Tacca, L. E. (2026). Management and diagnostic of productive efficiency in a biorefinery of oils obtained by supercritical fluid extraction from grape and lucuma seeds. Agroindustrial Science, 16(2), 209-218. https://doi.org/10.17268/agroind.sci.2026.02.03

Issue

Section

Artículos de investigación