Influence of hydrogen peroxide concentration on the detoxification of cyanide mine tailings
DOI:
https://doi.org/10.17268/rev.cyt.2023.02.02Keywords:
ANOVA, effluent treatment, mining industry, chemical treatment, cyanideAbstract
This research aims to compare two treatments for detoxification of cyanide mine tailings using hydrogen peroxide, the first one with a concentration of 50% and the second one with a concentration of 70%. The statistical tool ANOVA was used, together with the tukey method, to determine the differences and similarities of both treatments. The study was carried out in two trains composed of five tanks each, the treatment was randomized (DCA) for a period of 21 hours, obtaining a cyanide sample from each tank every hour. The results showed that the 70% peroxide treatment provides higher cyanide removal (<0.05 ppm), lower solvent consumption (975 kg) and lower consumption ratio (0.58 kg/m3), also, a solvent saving of 36% was obtained; the ANOVA analysis showed a significant influence between the peroxide concentration and cyanide removal, and also, that there is no relationship between the detoxification time and the final cyanide concentration for both treatments. In sum, the 70% peroxide treatment allows an effective cyanide removal, complying with the maximum permissible limits for its discharge, in accordance with the Peruvian legislation in force.
References
Ahsan, Q., Griffiths, A., Haug, E., y Norcross, R. (1990). Process for the removal of cyanide from wastewaters (Patent Núm. 4966715). En US Patent (Núm. 4966715). https://patents.google.com/patent/US4966715A/en
Akhgari, M., Baghdadi, F., y Kadkhodaei, A. (2016). Cyanide poisoning related deaths, a four-year experience and review of the literature. The Australian Journal of Forensic Sciences, 48(2), 186–194. https://doi.org/10.1080/00450618.2015.1045552
Amaouche, H., Chergui, S., Halet, F., Yeddou, A. R., Chergui, A., Nadjemi, B., y Ould-Dris, A. (2019). Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide catalyzed by copper oxide. Water Science and Technology: A Journal of the International Association on Water Pollution Research, 80(1), 126–133. https://doi.org/10.2166/wst.2019.254
Anning, C., Wang, J., Chen, P., Batmunkh, I., y Lyu, X. (2019). Determination and detoxification of cyanide in gold mine tailings: A review. Waste Management & Research: The Journal of the International Solid Wastes and Public Cleansing Association, ISWA, 37(11), 1117–1126. https://doi.org/10.1177/0734242X19876691
Aranguri LLerena, G., y Reyes López, I. A. (2018). Cyanide degradation from mining effluent using two reagents: Sodium metabisulphite and the metabisulphite mixture with hydrogen peroxide. TECCIENCIA, 13(25), 1–9. https://doi.org/10.18180/tecciencia.2018.25.1
Baharun, N., Ling, O. P., Rezaei Ardani, M., Ariffin, K. S., Yaraghi, A., Abdullah, N. S., Putra, T. A. R., y Ismail, S. (2020). Effect of hydrogen peroxide and lead(II) nitrate on gold cyanide leaching of Malaysian mesothermal deposit gold ore. Physicochemical Problems of Mineral Processing, 56(5), 905–918. https://doi.org/10.37190/ppmp/126629
Dong, K., Xie, F., Wang, W., Chang, Y., Lu, D., Gu, X., y Chen, C. (2021). The detoxification and utilization of cyanide tailings: A critical review. Journal of Cleaner Production, 302(126946), 126946. https://doi.org/10.1016/j.jclepro.2021.126946
Estrada-Montoya, C. C., Restrepo Franco, G. M., y Galeano Vanegas, N. F. (2020). Evaluation of cyanide and heavy metals removal in liquid effluents from small mining’s gold benefit, by adsorption with activated carbon and hydrogen peroxide in Segovia, Antioquia. Dyna, 87(212), 9–17. https://doi.org/10.15446/dyna.v87n212.79716
Griffiths, A. D., Dr. Ahsan, Q. M., Norcross, R., Knorre, H. D., y Merz, F. W. (1992). Process for the treatment of effluents containing cyanide and/or other oxidizable substances (Patent Núm. 0355417:B1). En European Patent (0355417:B1).
Griffiths, A., Knorre, H., Gos, S. y Higgins, R. (1987). The detoxification of gold-mill tailings with hydrogen peroxide. Journal of the Southern African Institute of Mining and Metallurgy, 87(9), 279-283. https://journals.co.za/doi/10.10520/AJA0038223X_1773
Hou, D., Liu, L., Yang, Q., Zhang, B., Qiu, H., Ruan, S., Chen, Y., y Li, H. (2020). Decomposition of cyanide from gold leaching tailingsby using sodium metabisulphite and hydrogen peroxide. Advances in Materials Science and Engineering, 2020, 1–7. https://doi.org/10.1155/2020/5640963
Hydrogen peroxide for mining. (2022, diciembre 6). Evonik.com. https://active-oxygens.evonik.com/en/markets/mining
Kitis, M., Akcil, A., Karakaya, E., y Yigit, N. O. (2005). Destruction of cyanide by hydrogen peroxide in tailings slurries from low bearing sulphidic gold ores. Minerals Engineering, 18(3), 353–362. https://doi.org/10.1016/j.mineng.2004.06.003
Krylova, L. N., Seliverstov, A. F., y Ryabtsev, D. A. (2021). Cleaning of industrial waters containing cyanides by using a combination of ozone and hydrogen peroxide. Metallurgist (USSR), 64(11–12), 1331–1339. https://doi.org/10.1007/s11015-021-01123-y
Labat, L., Dumestre-Toulet, V., Goullé, J. P., y Lhermitte, M. (2004). A fatal case of mercuric cyanide poisoning. Forensic Science International, 143(2–3), 215–217. https://doi.org/10.1016/j.forsciint.2004.02.039
Muboko, N., Muposhi, V., Tarakini, T., Gandiwa, E., Vengasayi, S., y Makuwe, E. (2014). Cyanide poisoning and African elephant mortality in Hwange National Park, Zimbabwe: A preliminary assessment. Pachyderm, 55, 92–94. http://library.wur.nl/WebQuery/wurpubs/483862
Ngulube, M. (2016). Elimination cyanide with hydrogen peroxide (H2O2) and calcium hypochlorite (ca(OCl)2) on Gold Mine waste from north luwu, south Sulawesi. American Journal of Environmental Protection, 5(4), 97. https://doi.org/10.11648/j.ajep.20160504.14
Pérez, B. F. (2007). Desarrollo de un nuevo método para la eliminación de cianuro de aguas residuales de mina. Universidad de Oviedo.
Rai, A., Chakrabarty, J., y Dutta, S. (2021). Phycoremediation of pollutants from coke-oven wastewater using Tetraspora sp. NITD 18 and estimation of macromolecules from spent biomass. Journal of Water Process Engineering, 39(101746), 101746. https://doi.org/10.1016/j.jwpe.2020.101746
Rapid Response Assessment, A. (s/f). Mine tailings storage: Safety is no accident. Amazonaws.com. Recuperado el 4 de febrero de 2023, de https://gridarendal-website-live.s3.amazonaws.com/production/documents/:s_document/371/original/RRA_MineTailings_lores.pdf?1510660693
Razali, N. M., y Wah, Y. B. (2011). Power comparisons of Shapiro-Wilk, Kolmogorov-Smirnov, Lilliefors and Anderson-Darling tests. https://www.semanticscholar.org/paper/dcdc0a0be7d65257c4e6a9117f69e246fb227423
Sanyaolu, N. O., Ibikunle, A. A., Kareem, F. A., Ogunmoye, A. O., Ogundare, S. A., Atewolara-Odule, O. C., Hashim, A. M., Akinwunmi, F., Adewuyi, S., Shittu, T., Eromosele, C. O., y Torto, N. (2021). Catalytic detoxification of aqueous cyanide using copper crown electrospun chitosan nanofiber. Journal of Chemical Society of Nigeria, 46(2). https://doi.org/10.46602/jcsn.v46i2.615
Tu, Y., Han, P., Wei, L., Zhang, X., Yu, B., Qian, P., y Ye, S. (2019). Removal of cyanide adsorbed on pyrite by H2O2 oxidation under alkaline conditions. Journal of Environmental Sciences (China), 78, 287–292. https://doi.org/10.1016/j.jes.2018.10.013
Tyagi, M., Rana, A., Kumari, S., y Jagadevan, S. (2018). Adsorptive removal of cyanide from coke oven wastewater onto zero-valent iron: Optimization through response surface methodology, isotherm and kinetic studies. Journal of Cleaner Production, 178, 398–407. https://doi.org/10.1016/j.jclepro.2018.01.016
Uppal, H., Tripathy, S. S., Chawla, S., Sharma, B., Dalai, M. K., Singh, S. P., Singh, S., y Singh, N. (2017). Study of cyanide removal from contaminated water using zinc peroxide nanomaterial. Journal of Environmental Sciences (China), 55, 76–85. https://doi.org/10.1016/j.jes.2016.07.011
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